Tetraaquabis(2-oxo-1,2-dihydropyridine-5-sulfonato-κO 2)zinc(II)
نویسندگان
چکیده
The metal atom in the title compound, [Zn(C(5)H(4)NO(4)S)(2)(H(2)O)(4)], lies on a center of inversion and is linked to the anionic ligand through the carbonyl O atom. In the crystal structure, the 2-oxo-1,2-dihydro-pyridine-5-sulfon-ate ligand inter-acts with other mol-ecules through N-H⋯O and O-H⋯O hydrogen bonds, forming a three-dimensional network structure.
منابع مشابه
Diaquabis(4-oxo-1,4-dihydropyridine-3-sulfonato-κ2 O 3,O 4)zinc(II)
In the crystal structure of the title compound, [Zn(C(5)H(4)NO(4)S)(2)(H(2)O)(2)], the 4-oxo-1,4-dihydro-pyridine-3-sulfonate anion chelates to water-coordinated zinc centres through the carbonyl O atom and through one O atom of the sulfonate group. The Zn(II) atom lies on a center of inversion, and adjacent mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds, forming a three-dimensional ne...
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In the title compound, [Ni(C(10)H(6)NO(3))(2)(H(2)O)(4)], the central Ni(II) atom is located on an inversion center and coordinated in a slightly distorted octa-hedral geometry by two O atoms from two 2-oxo-1,2-dihydro-quinoline-4-carboxyl-ate ligands and four water mol-ecules, all of which act as monodentate ligands. The crystal structure features an extensive network of inter-molecular hydrog...
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In the title mononuclear complex, [Zn(C(11)H(7)O(3))(2)(H(2)O)(4)], the Zn(II) atom is located on a centre of inversion and is coordinated by two O atoms from two 1-hydr-oxy-2-naphthoate ligands and four water mol-ecules in an octa-hedral geometry. The structure is consolidated by inter-molecular O-H⋯O hydrogen bonding, as well as by a π-π stacking inter-action [centroid-centroid distance 3.762...
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In the mol-ecule of the title compound, [Ni(C(5)H(4)NO(3)S)(2)(H(2)O)(4)], the Ni(II) cation is located on an inversion center and is coordinated by four water mol-ecules and two pyridine-3-sulfonate anions with an NiN(2)O(4) distorted octa-hedral geometry. The face-to-face separation of 3.561 (5) Å between parallel pyridine rings indicates the existence of weak π-π stacking between the pyridin...
متن کاملTetraaquabis(4-formylbenzoato-κO)cobalt(II) tetrahydrate
The Co(II) atom in the title compound, [Co(C(8)H(5)O(3))(2)(H(2)O)(4)]·4H(2)O, which exists in an all-trans octa-hedral coordination geometry, lies on a center of inversion. The coordinated and uncoordinated water mol-ecules engage in extensive hydrogen-bonding inter-actions, forming a three-dimensional hydrogen-bonded network.
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009